The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Peroxy radicals / Alkylperoxy / CH3O2 / Simon(1990)_300K_210-295nm

DATAFILE: CH3O2_Simon(1990)_300K_210-295nm.txt
NAME: methylperoxy radical
FORMULA: CH3O2
AUTHOR(YEAR): Simon(1990)
T: 300K
λ: 210-295nm
BIBLIOGRAPHY: F. Simon, W. Schneider, and G.K. Moortgat, "UV-absorption spectrum of the methylperoxy radical and the kinetics of its disproportionation reaction at 300 K", Int. J. Chem. Kinet. 22, 791-813 (1990); DOI: 10.1002/kin.550220802
COMMENTS: Molecular modulation spectroscopy combined with ultraviolet spectroscopic techniques have been used to observe the behavior of the CH3O2 radicals generated in the gas phase by near-ultraviolet modulated photolysis of flowing Cl2/CH4/O2 mixtures

Absorption cross sections with error limits as listed in Table IV

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